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Croissance in situ de nanoparticules d'or sur un réseau 3D constitué d'un nanocomposite MoS2 / rGO pour la détermination voltampérométrique simultanée de l'acide ascorbique, de la dopamine et de l'acide urique.

Une électrode en carbone vitreux a été modifiée avec une nanostructure en réseau 3D composée de MoS2, d'oxyde de graphène réduit et de nanoparticules d'or (3D-MoS2 / rGO / Au). Les composites ont été préparés par croissance in situ de nanoparticules d'or sur des feuilles miniatures 3D-MoS2 / rGO par une méthode hydrothermale. La morphologie et les caractéristiques électrochimiques du composite ont été étudiées. Le capteur 3D-MoS2 / rGO / Au présente une excellente activité électrocatalytique pour la détection simultanée d’acide ascorbique (AA), de dopamine (DA) et d’acide urique (UA). Les potentiels d'oxydation sont bien séparés à environ -0,05 V pour AA, 0,06 V pour DA et 0,2 V pour UA, respectivement. Les limites de détection pour la détection individuelle et la détection simultanée (S / N = 3) sont de 0,93 μM et 1,46 μM pour AA, 0,11 μM et 0,15 μM pour DA et de 0,74 μM et 0,29 μM pour UA. La méthode a été appliquée à l'analyse quantitative de AA, DA et UA dans des échantillons de sérum enrichis avec des résultats satisfaisants. Résumé graphique Croissance in situ de nanoparticules d’or sur nanocomposite MoS2 / rGO en réseau 3D pour la détermination individuelle et simultanée de l’acide ascorbique, de la dopamine et de l’acide urique.


Source: https://www.ncbi.nlm.nih.gov/pubmed/30631942


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