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Analyse Simultanée Sans Étiquette De Fe (III) Et D'acide Ascorbique En Utilisant La Commutation De Fluorescence De Nitrure De Carbone Graphitique Ultramince Nanosheets.

Une méthode simple d'oxydation chimique et d'exfoliation par ultrasons a été mise au point pour synthétiser les nanofeuilles en nitrure de carbone graphitique à deux couches et à couche ultra mince (g-C3N4). Les gN-C3N4 NN ultra-minces préparés présentent une forte fluorescence et une grande stabilité, notamment une bonne photostabilité et une excellente capacité antisal. Ici, un nouveau capteur de commutation fluorescent "on-off-on" est conçu. L'ion de fer (Fe (3+)) a une réponse ultrasensible pour atténuer la fluorescence des N-g-C3N4 en se basant sur l'effet synergique entre l'effet de filtre interne et le transfert d'électrons photo-induit. La limite linéaire pour Fe (3+) était comprise entre 0,05 et 30 molol L (-1) avec une limite de détection de 0,018 molol L (-1). Pendant ce temps, la fluorescence des N-g-C3N4 peut être récupérée par la réaction redox entre Fe (3+) et l’acide ascorbique (AA). De plus, la plage linéaire pour AA était comprise entre 0,2 et 112,5 molol L (-1) avec une limite de détection de 0,086 mololol L (-1). La méthode proposée a montré une réponse rapide, une excellente sélectivité, une large plage de détection et une limite de détection basse pour l'analyse simultanée de Fe (3+) et d'AA. Elle a également été appliquée pour la détermination de Fe (3+) et d'AA dans des échantillons d'eau et des échantillons humains. sérum avec des résultats satisfaisants.


Source: https://www.ncbi.nlm.nih.gov/pubmed/30010315


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