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Ag-dopage sur support ZnO à médiation par des bioanalytes riches en acide ascorbique pour la dégradation photocatalytique du médicament dipyrone.

Les analytes tels que l'acide ascorbique (AA) présent dans Sechium edule ont été extraits (294 mg AA kg (-1) de fruits) dans un milieu aqueux pour son application potentielle pour le dopage à l'Ag sur Zurt Wurtzite. La bande interdite de ZnO a été réduite à 2,85 eVat avec la charge en Ag optimale de 1,18% (p / p) contre 3,13 eV pour le catalyseur témoin sans utiliser les analytes et, seul l'AA du commerce pourrait réduire l'écart entre les bandes interdites à 2,91 eV. La densité de courant photo-électrochimique à saturation (46,68mAcm (-2)) à Eanode> / = 0,31V par rapport à Ag / AgCl était presque deux fois supérieure à celle du ZnO vierge sous éclairage à la lumière visible (lambdaméen = 525nm, 18K lux) et la densité de courant était insignifiant dans le noir. Le catalyseur dopé présentait la dégradation maximale de 79,5% (élimination de la DCO de 71%) d'un médicament anti-analgésique, la dipyrone (100 μgL -1), le catalyseur 100 μgL (-1) résultant de la formation de radicaux O2 (* -) ( facteur g de 2,002 à 2,008) et lacunes en oxygène paramagnétique (facteur g de 2,020) et aucun effet de la sensibilisation par un colorant n’a été noté. Le rendement quantique le plus élevé s'est révélé être de 34,7%. La perte de catalyseur était de 6% après le quatrième cycle et la dégradation de la dipyrone était réduite à 70,8%.


Source: https://www.ncbi.nlm.nih.gov/pubmed/29864706


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